We develop a continentality proxy (1600-1930) based on amplitudes of the annual signal in oxygen isotopes in an ice core. We show via modeling that by using 5 and 15 year average amplitudes the effects of diffusion and varying layer thickness can be minimized, such that amplitudes then reflect real seasonal changes in delta O-18 under the influence of melt. A model of chemical fractionation in ice based on differing elution rates for pairs of ions is developed as a proxy for summer melt (1130-1990). The best pairs are sodium with magnesium and potassium with chloride. The continentality and melt proxies are validated against twentieth-century instrumental records and longer historical climate proxies. In addition to summer temperature, the melt proxy also appears to reflect sea ice extent, likely as a result of sodium chloride fractionation in the oceanic sea ice margin source area that is dependent on winter temperatures. We show that the climate history they depict is consistent with what we see from isotopic paleothermometry. Continentality was greatest during the Little Ice Age but decreased around 1870, 20-30 years before the rise in temperatures indicated by the delta O-18 profile. The degree of summer melt was significantly larger during the period 1130-1300 than in the 1990s.

We examine the impact of melt water percolation on the soluble ion chemical record from the Lomonosovfonna ice core. Principle component analysis shows that melting produces only simple changes between bubbly and clear ice facies, due to elution of ions. The data can be naturally split into four groups: pre-industrial, immediately before, and after the end of the Little Ice Age, and anthropogenic impact eras. The 2nd, 3rd and 4th principle components for these periods all differ significantly, reflecting complex changes in environmental conditions. Thus the core preserves a rich record of environmental history, and simple one of melting. We construct a model of percolation effects to reconstruct "pristine'' ice chemical composition, finding that even with melt percentages as high as 80%, there is little disturbance to the chemical stratigraphy. This suggests that ionic records from Arctic ice cap cores are nearly as reliable as those from Greenland or Antarctica.