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Enhanced concentrations of dissolved gaseous mercury in the surface waters of the Arctic Ocean
Responsible organisation
2008 (English)In: Marine Chemistry, ISSN 0304-4203, E-ISSN 1872-7581, Vol. 110, no 3-4, 190-194 p.Article in journal (Refereed) Published
Abstract [en]

During an almost three months long expedition in the Arctic Ocean, the Beringia 2005, dissolved gaseous mercury (DGM) was measured continuously in the surface water. The DGM concentration was measured using an equilibrium system, i.e. the DGM in the water phase equilibrated with a stream of gas and the gas was thereafter analysed with respect to its mercury content. The DGM concentrations were calculated using the following equation, DGM = Hg-eq / k(H’) where Hg-eq is the equilibrated concentration of elemental mercury in the gas phase and k(H’) is the dimensionless Henry’s law constant at desired temperature and salinity. During the expedition several features were observed. For example, enhanced DGM concentration was measured underneath the ice which may indicate that the sea ice acted as a barrier for evasion of mercury from the Arctic Ocean to the atmosphere. Furthermore, elevated DGM concentrations were observed in water that might have originated from river discharge. The gas-exchange of mercury between the ocean and the atmosphere was calculated in the open water and both deposition and evasion were observed. The measurements showed significantly enhanced DGM concentrations, compared to more southern latitudes. (C) 2008 Elsevier B.V. All rights reserved.

Place, publisher, year, edition, pages
2008. Vol. 110, no 3-4, 190-194 p.
Keyword [en]
mercury; in situ measurements; Arctic Ocean; dissolved gaseous mercury; gas-exchange; biogeochemistry
National Category
Natural Sciences
Research subject
SWEDARCTIC 2005, Beringia 2005
Identifiers
URN: urn:nbn:se:polar:diva-3138DOI: 10.1016/j.marchem.2008.04.002OAI: oai:DiVA.org:polar-3138DiVA: diva2:1049830
Available from: 2016-11-25 Created: 2016-11-21 Last updated: 2016-11-25

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  • de-DE
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